In a recent paper we derived an expression for the replicated free energy of a liquid of hard spheres based on the hypernetted chain (HNC) free energy functional. An approximate equation of state for the glass and an estimate of the random close packing density were obtained for d = 3. Here we show that the HNC approximation is not needed: the same expression can be obtained from the full diagrammatic expansion of the replicated free energy. Then, we consider the asymptotics of this expression when the space dimension d is very large. In this limit, the entropy of the hard sphere liquid has been computed exactly. Using this solution, we derive asymptotic expressions for the glass transition density and for the random close packing density for hard spheres for large space dimension.

Amorphous packings of hard spheres for large space dimensions / Parisi, Giorgio; Zamponi, F.. - In: JOURNAL OF STATISTICAL MECHANICS: THEORY AND EXPERIMENT. - ISSN 1742-5468. - P03017:(2006), p. P03017. [10.1088/1742-5468/2006/03/P03017]

Amorphous packings of hard spheres for large space dimensions

PARISI, Giorgio;F. ZAMPONI
2006

Abstract

In a recent paper we derived an expression for the replicated free energy of a liquid of hard spheres based on the hypernetted chain (HNC) free energy functional. An approximate equation of state for the glass and an estimate of the random close packing density were obtained for d = 3. Here we show that the HNC approximation is not needed: the same expression can be obtained from the full diagrammatic expansion of the replicated free energy. Then, we consider the asymptotics of this expression when the space dimension d is very large. In this limit, the entropy of the hard sphere liquid has been computed exactly. Using this solution, we derive asymptotic expressions for the glass transition density and for the random close packing density for hard spheres for large space dimension.
2006
Glass transition; fluctuations; statistical mechanics
01 Pubblicazione su rivista::01a Articolo in rivista
Amorphous packings of hard spheres for large space dimensions / Parisi, Giorgio; Zamponi, F.. - In: JOURNAL OF STATISTICAL MECHANICS: THEORY AND EXPERIMENT. - ISSN 1742-5468. - P03017:(2006), p. P03017. [10.1088/1742-5468/2006/03/P03017]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/6378
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