Visual appearance and scratch resistance of high performance thermoset and thermoplastic powder coatings

A comparative evaluation of electrostatic spray and 'hot dipping' fluidized bed to deposit two different organic paints belonging to the class of thermoplastic (PPA571, an alloy of acid modified polyolefins) and thermoset (TGIC-free transparent pigmented bronze polyester) powders was performed. Visual appearance of the investigated coatings was evaluated by colour, gloss and coating thickness measurements as well as by the determination of the surface morphologies. Micro-mechanical performance of the coatings was assessed by progressive load scratch tests. 'Hot dipping' fluidized bed is found a fast deposition technique as, after substrate pre-heating, it takes just few seconds to have the part completely powder coated. On the other hand, electrostatic spray deposition is a potentially selective coating technique, but it lasts longer (generally, 6-15 s) and, moreover, the coated parts must be post-cured for long time (at least, 15 min) and at high temperature (150-200 °C) to give rise to the formation of continuous films. Indeed, whilst 'hot dipping' fluidized bed is found particularly suitable for the deposition of thick and smooth thermoplastic coatings, electrostatic spray deposition is found the most viable technique to deposit thinner and highly scratch and wear resistant thermoset coatings.

A comparative evaluation of electrostatic spray and 'hot dipping' fluidized bed to deposit two different organic paints belonging to the class of thermoplastic (PPA571, an alloy of acid modified polyolefins) and thermoset (TGIC-free transparent pigmented bronze polyester) powders was performed. Visual appearance of the investigated coatings was evaluated by colour, gloss and coating thickness measurements as well as by the determination of the surface morphologies. Micro-mechanical performance of the coatings was assessed by progressive load scratch tests. 'Hot dipping' fluidized bed is found a fast deposition technique as, after substrate pre-heating, it takes just few seconds to have the part completely powder coated. On the other hand, electrostatic spray deposition is a potentially selective coating technique, but it lasts longer (generally, 6-15 s) and, moreover, the coated parts must be post-cured for long time (at least, 15 min) and at high temperature (150-2000 degrees C) to give rise to the formation of continuous films. Indeed, whilst 'hot dipping' fluidized bed is found particularly suitable for the deposition of thick and smooth thermoplastic coatings, electrostatic spray deposition is found the most viable technique to deposit thinner and highly scratch and wear resistant thermoset coatings. (C) 2012 Elsevier B.V. All rights reserved.