Dispersion properties of biomolecules in size-exclusion chromatographic columns are analyzed both experimentally and theoretically. In order to explain tile linear behaviour of the dispersion coefficient with tile solute velocity, experimentally found for most of the biomolecules considered, a stochastic model of solute dispersion is proposed based on the exit-time equation.
STOCHASTIC-ANALYSIS OF DISPERSION IN SIZE-EXCLUSION CHROMATOGRAPHIC COLUMNS / Adrover, Alessandra; D., Barba; Giona, Massimiliano; D., Spera. - STAMPA. - 87:(1994), pp. 373-382. (Intervento presentato al convegno IUPAC Symposium on Characterization of Porous Solids (COPS III) tenutosi a MARSEILLE, FRANCE nel MAY 09-12, 1993).
STOCHASTIC-ANALYSIS OF DISPERSION IN SIZE-EXCLUSION CHROMATOGRAPHIC COLUMNS
ADROVER, Alessandra;GIONA, Massimiliano;
1994
Abstract
Dispersion properties of biomolecules in size-exclusion chromatographic columns are analyzed both experimentally and theoretically. In order to explain tile linear behaviour of the dispersion coefficient with tile solute velocity, experimentally found for most of the biomolecules considered, a stochastic model of solute dispersion is proposed based on the exit-time equation.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
