Labeled daughter ions from the decay of selectively multitritiated toluenes were trapped with MeOH(g) at different pressures. The ions from C6X5Me (X = H, T) yield tritiated Me tolyl ethers, while those from PhCX3 yield exclusively tritiated benzyl Me ether. The primary decay ions retain their cyclic structure, without collapsing to the tropylium ion, at least during the time (10-9 to 10-7 s) required for their trapping by the gaseous nucleophile.
Trapping with gaseous methanol the C7H7+ daughter ions from the decay of tritiated toluenes / Cacace, Fulvio; G., Ciranni; C., Sparapani; Speranza, Maurizio. - In: RADIOCHIMICA ACTA. - ISSN 0033-8230. - STAMPA. - 35:(1984), pp. 195-198.
Trapping with gaseous methanol the C7H7+ daughter ions from the decay of tritiated toluenes
CACACE, Fulvio;SPERANZA, Maurizio
1984
Abstract
Labeled daughter ions from the decay of selectively multitritiated toluenes were trapped with MeOH(g) at different pressures. The ions from C6X5Me (X = H, T) yield tritiated Me tolyl ethers, while those from PhCX3 yield exclusively tritiated benzyl Me ether. The primary decay ions retain their cyclic structure, without collapsing to the tropylium ion, at least during the time (10-9 to 10-7 s) required for their trapping by the gaseous nucleophile.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.