The binding affinities of tetramethylammonium chloride to uranyl salophen receptors decorated with X-substituted aromatic pendants (X = OCH3, CH3, H, Br, NO2) point to the importance of resonance effects in cation-pi interactions, at variance with the view that field/inductive effects play a dominant role.
Substituent effects in cation-pi interactions. Recognition of tetramethylammonium chloride by uranyl-salophen receptors / Massimo, Cametti; DALLA CORT, Antonella; Mandolini, Luigi. - In: CHEMICAL SCIENCE. - ISSN 2041-6520. - STAMPA. - 3:6(2012), pp. 2119-2122. [10.1039/c2sc00675h]
Substituent effects in cation-pi interactions. Recognition of tetramethylammonium chloride by uranyl-salophen receptors
DALLA CORT, Antonella;MANDOLINI, Luigi
2012
Abstract
The binding affinities of tetramethylammonium chloride to uranyl salophen receptors decorated with X-substituted aromatic pendants (X = OCH3, CH3, H, Br, NO2) point to the importance of resonance effects in cation-pi interactions, at variance with the view that field/inductive effects play a dominant role.File allegati a questo prodotto
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
