The valence electronic structure of epichlorohydrin, because of its importance as a model chiral system, has been investigated by Angle-Resolved- and Threshold-Photoelectron Spectroscopies (ARPES and TPES) using circular and linear polarized light. The controversial assignments of the valence electronic structure of the molecule impede a full understanding of chiroptical properties such as the circular dichroism exhibited in the valence photoelectron angular distribution of its enantiomers. Addressing this issue by a combined experimental and theoretical investigation is here highlighted.
The valence electronic structure and conformational flexibility of epichlorohydrine / M., Alagia; Stranges, Stefano; P., Decleva; M., Stener; G, Fronzoni; D., Toffoli; Speranza, Maurizio; D., Catone; S., Turchini; T., Prosperi; N., Zema; G., Contini; Y., Keheyan. - STAMPA. - (2011), pp. 16-17.
The valence electronic structure and conformational flexibility of epichlorohydrine
STRANGES, Stefano;SPERANZA, Maurizio;
2011
Abstract
The valence electronic structure of epichlorohydrin, because of its importance as a model chiral system, has been investigated by Angle-Resolved- and Threshold-Photoelectron Spectroscopies (ARPES and TPES) using circular and linear polarized light. The controversial assignments of the valence electronic structure of the molecule impede a full understanding of chiroptical properties such as the circular dichroism exhibited in the valence photoelectron angular distribution of its enantiomers. Addressing this issue by a combined experimental and theoretical investigation is here highlighted.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
