Protonation by gaseous H+3, CnH+5 (n=1,2), s-C3H+7 and t-C4H+9 cations promotes rearrangement of cyclopentane- and cyclohexanecarboxaldehyde to cyclohexanone and cyclopentylmethyl ketone, respectively. The reaction was investigated by radiolytic and mass spectrometric methods.
Acid-catalyzed aldehyde-ketone rearrangements in the gas phase. Cyclopentane- and cyclohexanecarboxaldehyde / Giacomello, Pierluigi; Adriano, Pizzabiocca; Gabriele, Renzi; Speranza, Maurizio. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 24:38(1983), pp. 4157-4160. [10.1016/s0040-4039(00)88287-8]
Acid-catalyzed aldehyde-ketone rearrangements in the gas phase. Cyclopentane- and cyclohexanecarboxaldehyde.
GIACOMELLO, Pierluigi;SPERANZA, Maurizio
1983
Abstract
Protonation by gaseous H+3, CnH+5 (n=1,2), s-C3H+7 and t-C4H+9 cations promotes rearrangement of cyclopentane- and cyclohexanecarboxaldehyde to cyclohexanone and cyclopentylmethyl ketone, respectively. The reaction was investigated by radiolytic and mass spectrometric methods.File allegati a questo prodotto
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