The first 1,2-Brook rearrangements with bis(dimethyl-phenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
Studies on the 1,2-Brook Rearrangement of Bissilyl Ketones / Andreas, Kirschning; Silke, Luiken; Migliorini, Antonella; Loreto, Maria Antonietta; Monika, Vogt. - In: SYNLETT. - ISSN 0936-5214. - STAMPA. - 2009:3(2009), pp. 429-432. [10.1055/s-0028-1087535]
Studies on the 1,2-Brook Rearrangement of Bissilyl Ketones
MIGLIORINI, Antonella;LORETO, Maria Antonietta;
2009
Abstract
The first 1,2-Brook rearrangements with bis(dimethyl-phenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.File allegati a questo prodotto
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