The local structure of Nb3Ge intermetallic superconductor has been studied by Ge K-edge absorption spectroscopy. Extended x-ray absorption fine structure (EXAFS) experiments show two Ge-Nb distances. In addition to the crystallographic distance of similar to2.87 Angstrom, there exists a second Ge-Nb distance, shorter than the first by similar to0.2 Angstrom, assigned to a phase with short-range symmetry related to local displacements in the Nb-Nb chains. The x-ray absorption near-edge structure (XANES) spectrum has been simulated by full multiple-scattering calculations considering the local displacements determined by the EXAFS analysis. The XANES spectrum has been well reproduced by considering a cluster of 99 atoms within a radius of about 7 Angstrom from the central Ge atom and introducing determined local displacements.
A study of the Nb3Ge system by Ge K-edge extended x-ray absorption fine structure and x-ray absorption near-edge structure spectroscopy / Saini, Naurang Lal; M., Filippi; Ziyu, Wu; H., Oyanagi; H., Ihara; A., Iyo; S., Agrestini; Bianconi, Antonio. - In: JOURNAL OF PHYSICS. CONDENSED MATTER. - ISSN 0953-8984. - STAMPA. - 14:(2002), pp. 13543-13550. [10.1088/0953-8984/14/49/310]
A study of the Nb3Ge system by Ge K-edge extended x-ray absorption fine structure and x-ray absorption near-edge structure spectroscopy
SAINI, Naurang Lal;BIANCONI, Antonio
2002
Abstract
The local structure of Nb3Ge intermetallic superconductor has been studied by Ge K-edge absorption spectroscopy. Extended x-ray absorption fine structure (EXAFS) experiments show two Ge-Nb distances. In addition to the crystallographic distance of similar to2.87 Angstrom, there exists a second Ge-Nb distance, shorter than the first by similar to0.2 Angstrom, assigned to a phase with short-range symmetry related to local displacements in the Nb-Nb chains. The x-ray absorption near-edge structure (XANES) spectrum has been simulated by full multiple-scattering calculations considering the local displacements determined by the EXAFS analysis. The XANES spectrum has been well reproduced by considering a cluster of 99 atoms within a radius of about 7 Angstrom from the central Ge atom and introducing determined local displacements.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
