The mechanism of polyacetylene [25067-58-7] cis-trans isomerization was investigated. The isomerization occurs through the cleavage of a double bond with radical formation. The presence of O accelerates the isomerization, probably through interaction with polymer double bonds.
EPR AND IR INVESTIGATION ON CIS-TRANS ISOMERIZATION AND OXIDATION OF POLYACETYLENE FILMS / A., Zanobi; D'Ilario, Lucio. - In: JOURNAL DE PHYSIQUE. COLLOQUE. - ISSN 0449-1947. - STAMPA. - 44:C3(1983), pp. C3-309-C3-311. [10.1051/jphyscol:1983360]
EPR AND IR INVESTIGATION ON CIS-TRANS ISOMERIZATION AND OXIDATION OF POLYACETYLENE FILMS
D'ILARIO, LUCIO
1983
Abstract
The mechanism of polyacetylene [25067-58-7] cis-trans isomerization was investigated. The isomerization occurs through the cleavage of a double bond with radical formation. The presence of O accelerates the isomerization, probably through interaction with polymer double bonds.File allegati a questo prodotto
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