The synthesis of a new chiral nosyloxycarbamate derived from Helmchen's auxiliary is described. Reactions performed with this aminating reagent successfully give the formation of diastereomeric allylic carbamates or diastereomeric aziridines starting from different kinds of olefins.
Reagent Controlled Diastereoselective Aminations with a New Chiral Nosyloxycarbamate / Fioravanti, Stefania; Morreale, Alberto; Pellacani, Lucio; Tardella, Paolo Antonio. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 44:(2003), pp. 3031-3034. [10.1016/S0040-4039(03)00558-6]
Reagent Controlled Diastereoselective Aminations with a New Chiral Nosyloxycarbamate
FIORAVANTI, Stefania;MORREALE, Alberto;PELLACANI, Lucio;TARDELLA, Paolo Antonio
2003
Abstract
The synthesis of a new chiral nosyloxycarbamate derived from Helmchen's auxiliary is described. Reactions performed with this aminating reagent successfully give the formation of diastereomeric allylic carbamates or diastereomeric aziridines starting from different kinds of olefins.File allegati a questo prodotto
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