The isomorphic substitution applied to solutions of NH4PtCl4 and NH4PdCl4 allows to show the existence of 2 bound water molecules at the apical sites of PtCl42- and PdCl42- ions. The Pt(Pd)-H2O distance results equal to 2.77 Angstrom

Palladium (II) and platinum (II) aqueous solutions. Evidence for the solvation of the [PdCl4](2-) and [PtCl4](2-) ions / Caminiti, Ruggero; Sadun, Claudia; M., Carbone. - In: JOURNAL OF MOLECULAR LIQUIDS. - ISSN 0167-7322. - STAMPA. - 75:(1998), pp. 149-158. [10.1016/S0167-7322(98)82003-5]

Palladium (II) and platinum (II) aqueous solutions. Evidence for the solvation of the [PdCl4](2-) and [PtCl4](2-) ions

CAMINITI, Ruggero;SADUN, Claudia;
1998

Abstract

The isomorphic substitution applied to solutions of NH4PtCl4 and NH4PdCl4 allows to show the existence of 2 bound water molecules at the apical sites of PtCl42- and PdCl42- ions. The Pt(Pd)-H2O distance results equal to 2.77 Angstrom
1998
X-RAY-DIFFRACTION; SQUARE-PLANAR SUBSTITUTIONS; PRESSURE NMR KINETICS; DIMETHYL-SULFOXIDE; WATER-EXCHANGE; VARIABLE-TEMPERATURE; AQUA COMPLEXES; CHLORO-AQUA; MECHANISM; TETRAAQUAPLATINUM(II)
01 Pubblicazione su rivista::01a Articolo in rivista
Palladium (II) and platinum (II) aqueous solutions. Evidence for the solvation of the [PdCl4](2-) and [PtCl4](2-) ions / Caminiti, Ruggero; Sadun, Claudia; M., Carbone. - In: JOURNAL OF MOLECULAR LIQUIDS. - ISSN 0167-7322. - STAMPA. - 75:(1998), pp. 149-158. [10.1016/S0167-7322(98)82003-5]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/247554
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