Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of C H acid-containing compounds vs. catalytic addition pro- cesses. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a cata-lytic amount of electricity under galvanostatic condi- tions.
Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte / T., Caruso; Feroci, Marta; Inesi, Achille; M., Orsini; A., Scettri; L., Palombi. - In: ADVANCED SYNTHESIS & CATALYSIS. - ISSN 1615-4150. - STAMPA. - 348:(2006), pp. 1942-1947. [10.1002/adsc.200606082]
Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte
FEROCI, Marta;INESI, ACHILLE;
2006
Abstract
Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of C H acid-containing compounds vs. catalytic addition pro- cesses. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a cata-lytic amount of electricity under galvanostatic condi- tions.| File | Dimensione | Formato | |
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46. Ad.Syn.Cat.2006, 348, 1924-1947.pdf
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