The oxywater cation H2 OO+ was generated in the gas phase by ionization of mixtures containing O3, O2 and H2 O. Different ionic mixtures, rich in either the H2 OO+ or the HOOH+ isomer, were obtained by O3 /O2 /H2 O–O2 /H2 O CI, and by CH3 OH/O2 –CH2 O/O2 CI, respectively. The H2 O2+ ions were characterized by high-resolution CAD mass spectrometry, and structural and energetic effects were examined.
A Novel route to H2O2+° ions via direct generation of the oxywater cation H2OO+° / DE PETRIS, Giulia; Cartoni, Antonella; Cipollini, Romano; Troiani, Anna. - In: INTERNATIONAL JOURNAL OF MASS SPECTROMETRY. - ISSN 1387-3806. - STAMPA. - 249-250:(2006), pp. 311-316. [10.1016/j.ijms.2005.12.010]
A Novel route to H2O2+° ions via direct generation of the oxywater cation H2OO+°
DE PETRIS, GIULIA;CARTONI, Antonella;CIPOLLINI, Romano;TROIANI, Anna
2006
Abstract
The oxywater cation H2 OO+ was generated in the gas phase by ionization of mixtures containing O3, O2 and H2 O. Different ionic mixtures, rich in either the H2 OO+ or the HOOH+ isomer, were obtained by O3 /O2 /H2 O–O2 /H2 O CI, and by CH3 OH/O2 –CH2 O/O2 CI, respectively. The H2 O2+ ions were characterized by high-resolution CAD mass spectrometry, and structural and energetic effects were examined.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
