The hydrophilic vs. hydrophobic balance for five C-60 derivatives (FD1-5) bearing one hydrophilic addend has been evaluated by means of useful descriptors derived from (i) aggregation measurements in aqueous/organic mixtures, (ii) partition measurements between n-octanol and water (109 P-m/a), and (iii) retention factors in reverse-phase chromatography (log k(w)). Aggregates of FD1-5 have been obtained both in water and in aqueous organic mixtures. The dimension of the aggregates has been estimated by gel-permeation chromatography. © Wiley-VCH Verlag GmbH & Co. KGaA.
The associative properties of some amphiphilic fullerene derivatives / Guido, Angelini; Claudia, Cusan; Paolo De, Maria; Antonella, Fontana; Michele, Maggini; Pierini, Marco; Maurizio, Prato; Stefano, Schergna; Villani, Claudio. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - 2005:9(2005), pp. 1884-1891. [10.1002/ejoc.200400699]
The associative properties of some amphiphilic fullerene derivatives
PIERINI, MARCO;VILLANI, Claudio
2005
Abstract
The hydrophilic vs. hydrophobic balance for five C-60 derivatives (FD1-5) bearing one hydrophilic addend has been evaluated by means of useful descriptors derived from (i) aggregation measurements in aqueous/organic mixtures, (ii) partition measurements between n-octanol and water (109 P-m/a), and (iii) retention factors in reverse-phase chromatography (log k(w)). Aggregates of FD1-5 have been obtained both in water and in aqueous organic mixtures. The dimension of the aggregates has been estimated by gel-permeation chromatography. © Wiley-VCH Verlag GmbH & Co. KGaA.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
