The use of peroxycarboxylic-acid-functionalized hexagonal mesoporous silica (HMS) as an oxidizing solid agent was investigated. The experimentation was performed on organic sulfur compounds that have been selected as representative of those contained in crude distillates. The results clearly show the potentiality of this oxidizing agent for the development of oxidative desulfurization (ODS) processes for the purpose of producing ultralow-sulfur fuels and sulfoxides and sulfones as secondary products. © 2008 American Chemical Society.
Functionalized hexagonal mesoporous silica as an oxidizing agent for the oxidative desulfurization of organosulfur compounds / DE FILIPPIS, Paolo; Scarsella, Marco. - In: INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. - ISSN 0888-5885. - STAMPA. - 47:3(2008), pp. 973-975. [10.1021/ie071057y]
Functionalized hexagonal mesoporous silica as an oxidizing agent for the oxidative desulfurization of organosulfur compounds
DE FILIPPIS, Paolo;SCARSELLA, Marco
2008
Abstract
The use of peroxycarboxylic-acid-functionalized hexagonal mesoporous silica (HMS) as an oxidizing solid agent was investigated. The experimentation was performed on organic sulfur compounds that have been selected as representative of those contained in crude distillates. The results clearly show the potentiality of this oxidizing agent for the development of oxidative desulfurization (ODS) processes for the purpose of producing ultralow-sulfur fuels and sulfoxides and sulfones as secondary products. © 2008 American Chemical Society.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
