Modeling ionic reactions in a dynamic environment, such as in a solvent cage, requires the generation of tailor-made ionic adducts involved in the process and the investigation of the intrinsic structural and electronic factors governing their behavior in the unsolvated state. A compendium of the most recent studies on the gas-phase dynamics and reactivity of chiral ion-dipole pairs involved in classical organic reactions is reported, together with a presentation of the experimental and,theoretical methodologies adopted. Copyright (C) 2004 John Wiley Sons, Ltd.
Dynamics and reactivity of chiral ion-dipole pairs / Speranza, Maurizio. - In: JOURNAL OF PHYSICAL ORGANIC CHEMISTRY. - ISSN 0894-3230. - STAMPA. - 18:2(2005), pp. 90-95. (Intervento presentato al convegno 7th Latin American Conference on Physical Organic Chemistry tenutosi a Florianopolis, BRAZIL nel SEP, 2003) [10.1002/poc.860].
Dynamics and reactivity of chiral ion-dipole pairs
SPERANZA, Maurizio
2005
Abstract
Modeling ionic reactions in a dynamic environment, such as in a solvent cage, requires the generation of tailor-made ionic adducts involved in the process and the investigation of the intrinsic structural and electronic factors governing their behavior in the unsolvated state. A compendium of the most recent studies on the gas-phase dynamics and reactivity of chiral ion-dipole pairs involved in classical organic reactions is reported, together with a presentation of the experimental and,theoretical methodologies adopted. Copyright (C) 2004 John Wiley Sons, Ltd.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
