Reliable determination of the enantiomeric excess of free amino acids can be obtained by measuring the induced circular dichroism of a multicomponent assembly formed by a modified tris(2-pyridylmethyl)amine ligand, a zinc salt, and the amino acid of interest. The systems furnish reliable information for all natural amino acids. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Determination of amino acid enantiopurity and absolute configuration: synergism between configurationally labile metal-based receptors and dynamic covalent interactions / Scaramuzzo, F. A.; Licini, G.; Zonta, C.. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 19:49(2013), pp. 16809-16813. [10.1002/chem.201302721]
Determination of amino acid enantiopurity and absolute configuration: synergism between configurationally labile metal-based receptors and dynamic covalent interactions
Scaramuzzo F. A.;
2013
Abstract
Reliable determination of the enantiomeric excess of free amino acids can be obtained by measuring the induced circular dichroism of a multicomponent assembly formed by a modified tris(2-pyridylmethyl)amine ligand, a zinc salt, and the amino acid of interest. The systems furnish reliable information for all natural amino acids. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.| File | Dimensione | Formato | |
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